Hello Van Rue,
With 127.0.0.1 connection, you have access to StarWind storage locally, without network card involvment. This connection should work in any case if StarWind device status is Synchronized.
According to KB article
https://knowledgebase.starwindsoftware. ... correctly/, with 10 Gbps iSCSI connection, it is recommended to use Round Robin MPIO policy.
In case if you want to have one more redundant iSCSI channel, you can "play" with other MPIO policies, for example Round Robin with Subset.